Entropic effects on the size dependence of cluster structure.
نویسندگان
چکیده
We show that the vibrational entropy can play a crucial role in determining the equilibrium structure of clusters by constructing structural phase diagrams showing how the structure depends upon both size and temperature. These phase diagrams are obtained for example rare gas and metal clusters.
منابع مشابه
Molecular Dynamics Simulation of Al Energetic Nano Cluster Impact (ECI) onto the Surface
On the atomic scale, Molecular Dynamic (MD) Simulation of Nano Al cluster impact on Al (100) substrate surface has been carried out for energies of 1-20 eV/atom to understand quantitatively the interaction mechanisms between the cluster atoms and the substrate atoms. The many body Embedded Atom Method (EAM) was used in this simulation. We investigated the maximum substrate temperature Tmax and...
متن کاملSize Evolution Study of the Electronic and Magnetic Properties of MgO Nanoclusters
Magnesium oxide nanoclusters have attracted much attention due to their potential applications to catalysis and novel optoelectronic materials. In the present study, we have studied the electronic and magnetic properties of the stoichiometric magnesium oxide nanoclusters (MgO)n for n = 2-20. Although the binding energy increases with the size of the cluster, it re...
متن کاملA study on the dependence of DC electrical properties and nanostructure of Cu thin films on film thickness
This paper reports the correlation between film thickness, nanostructure and DC electrical properties of copper thin films deposited by PVD method on glass substrate. X-ray diffraction (XRD) and atomic force microscopy (AFM) were used for crystallography and morphology investigation, respectively. Resistivity was measured by four point probe instrument, while a Hall effects measurement system w...
متن کاملA study on the dependence of DC electrical properties and nanostructure of Cu thin films on film thickness
This paper reports the correlation between film thickness, nanostructure and DC electrical properties of copper thin films deposited by PVD method on glass substrate. X-ray diffraction (XRD) and atomic force microscopy (AFM) were used for crystallography and morphology investigation, respectively. Resistivity was measured by four point probe instrument, while a Hall effects measurement system w...
متن کاملThe size dependence of the electronic structure of Pd clusters supported on A1203/Re(0001)
The size dependence of the electronic structure of Pd clusters deposited on an ordered Al203 film on Re(0001 ) has been studied using angle-resolved photoemission in conjunction with synchrotron radiation. The appearance of dispersion effects along directions both parallel and perpendicular to the substrate surface with increasing cluster size is observed, which is attributed to the formation o...
متن کاملذخیره در منابع من
با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید
برای دانلود متن کامل این مقاله و بیش از 32 میلیون مقاله دیگر ابتدا ثبت نام کنید
ثبت ناماگر عضو سایت هستید لطفا وارد حساب کاربری خود شوید
ورودعنوان ژورنال:
- Physical review letters
دوره 86 16 شماره
صفحات -
تاریخ انتشار 2001